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Product Details:
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Color: | White Powder | SiO2/Al2O3: | 25-40 |
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BET: | 450 | Application: | Catalytic Oxidation Catalyst,is Widely Used In Oxidation, Epoxidation And Amidoximation Reaction |
CAS: | 1318-02-1 | ||
High Light: | CAS 1318 02 1 TS-1 Zeolite,SiO2/TiO2 40 ts 1 zeolite catalyst,SiO2/TiO2 40 ts 1 zeolite catalyst |
TS-1 titanium silicon molecular sieve
Index | Unit | Figure | ||
Index of single digit (SiO2/TiO2) | The molar ratio | 25-40 | ||
The sodium content of | Wt% | 0.01% | ||
The grain size of | um | 0.2-0.4 | ||
Bulk Density | g/ml | 0.55±0.1 | ||
specific surface area g | m2/g | ≥450 | ||
Water content | Wt% | < 2% | ||
Packing | Bag/drum | 25kg | ||
The reaction performance of amine oxime | ||||
Raw material conversion rate (%) | ≥99.9% | |||
The epoxidation reaction performance(%) | ≥99% | |||
The one-way service life | ≥240hour | |||
The total life | ≥3000hour | |||
The properties of epoxy reaction | ||||
The epoxidation reaction performance(%) | ≥99.9% | |||
Product selectivity (%) | ≥95% | |||
Life | ≥400hour |
Features
TS-1 Molecular Sieve Ti atoms replace part of aluminum atoms insilicon aluminium molecular sieve and into, which belongs to ZSM-5 series zeolite molecular sieve, with the MFI structure, composed ofsilicon oxygen tetrahedron and titanium oxygen tetrahedron primarystructural unit, connecting through the oxygen bridge, constitute asecondary structure unit of five membered rings, and further to form a three-dimensional porous skeleton, pore structure with two-dimensional MFI molecular sieve, parallel to the a axis of the ten membered ring is in a S shape, aperture of 0.51nm * 0.55nm, ten membered ring and linearly parallel to the b axis direction,aperture of 0.54nm * 0.56nm.
TS-1 zeolite introduction
As an environmentally benign catalyst, the successful synthesis of titanium silicalite molecular sieve (TS-1) has been considered to be a milestone in zeolite catalysis as of the 1980sbecause of its unique catalytic performance in oxidation reaction involving H2O2 as an oxidant.1 TS-1 zeolite has the same skeletal structure (MFI) as ZSM-5. It possesses bi-directional 10-membered ring pore systems with the pore size along (100) as 5.1×5.5 Å and 5.3×5.6 Å along (010) (Figure 1).2 Ti species in TS-1 exist in three different forms, with only the tetrahedral Ti species in the framework being able to express high selectivity while the octahedral Ti species and anatase-TiO2 crystals reduce the utilization of hydrogen peroxide3.
TS-1 Molecular Sieve has a three-dimensional pore structure is composed of two sets of ten membered ring channel and a set of ninemembered ring channel interleaving composition, molar group has become (0.001 ~ 0.2) TiO2: SiO2.
UseTS-1 Molecular Sieve is produced by our company, the averagediameter of 50-60m, minimum close to 10m, the maximum is less than 105m, uniform particle size distribution.TS-1 Molecular Sievecan be used as catalytic oxidation catalyst,is widely used in oxidation, epoxidation and amidoximation reaction.For example, a catalyst for the production of propylene oxide,catalyst for the production of cyclohexanone oxime.
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